Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Blue-shifted Hydrogen Bonds with Proton-donors Incapable of Rehybridization
Jin-Ti WangYong FengLei LiuXiao-Song LiQing-Xiang Guo
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2003 Volume 32 Issue 8 Pages 746-747

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Abstract

Blue-shifted hydrogen bonds were found for F–He–H···Y (Y = N2, CO, and He) systems where the proton-donor (He) was incapable of rehybridization. This finding indicated that rehybridization is not a generally applicable driving force for the blue shift.

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© 2003 The Chemical Society of Japan
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