Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Enantiomeric Resolution of Intramolecular Amine–Borane Complex with a Chiral Boron Center
Shinji ToyotaTomohiro HakamataNaoya NittaFumiko Ito
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2004 Volume 33 Issue 3 Pages 206-207

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Abstract

The enantiomers of [2-(dimethylaminomethyl)phenyl](pentafluoropropionyloxy)phenylborane were successfully resolved by chiral HPLC as a new type of intramolecular amine–borane complex with a chiral center at the tetrahedral boron atom. The X-ray structure, the barrier to racemization, and the chiroptical properties are reported.

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© 2004 The Chemical Society of Japan
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