Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Direct Observation of the Li+–18-Crown-6 Complex Working as H2O Capture in Acetone–Water Mixture
Yoichi KikuchiKayoko HaramotoShunsuke MochizukiAkihiro Wakisaka
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2004 Volume 33 Issue 3 Pages 214-215

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Abstract

The complex formation of alkali metal ion (Li+ or Na+) with 18-crown-6 in an acetone–water mixed solvent was studied by means of the specially designed mass spectrometer. The Li+–18-crown-6 complex can hold one H2O in its cavity in the mixed solvent, whereas the Na+–18-crown-6 complex hardly holds an H2O.

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© 2004 The Chemical Society of Japan
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