Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Direct Alkylation and Phenylation of 3,8-Dibromo-1,10-phenanthroline with Grignard Reagents
Kazushige AnzaiHiroki FukumotoTakakazu Yamamoto
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2004 Volume 33 Issue 3 Pages 252-253

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Abstract

Reactions of alkyl and phenyl Grignard reagents with 3,8-dibromo-1,10-phenanthroline led to alkylation and phenylation at the 2-position of 1,10-phenanthroline. The prepared 2-alkyl-1,10-phenanthroline forms a 1:1 complex with Cu(II) and serves as a starting material for poly(2-alkyl-1,10-phenanthroline-3,8-diyl).

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© 2004 The Chemical Society of Japan
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