Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
A Cationic Diruthenium Amidinate, [(η5-C5Me5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C5Me5)]+, as an Efficient Catalyst for the Atom-Transfer Radical Reactions
Yukihiro MotoyamaMitsuru GondoSatoshi MasudaYuya IwashitaHideo Nagashima
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Volume 33 (2004) Issue 4 Pages 442-443

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Abstract

A cationic diruthenium amidinate, [(η5-C5Me5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C5Me5)]+, is generated by treatment of (η5-C5Me5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(Cl)(η5-C5Me5) (3a) with NaPF6 or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of N-allyl trichloroacetamides and related reactions.

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© 2004 The Chemical Society of Japan
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