Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Solvatochromic Shift of Phthalocyanine Q-band Governed by a Single Solvent Parameter
Hiroaki IsagoYutaka KagayaAkiyuki Matsushita
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2004 年 33 巻 7 号 p. 862-863

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Position of the main optical absorption band (Q-band) in electronic spectra of some trans-[M(Pc)L2]k (Pc = substituted or unsubstituted phthalocyaninate, M = Co(III), L = CN, k = −1; M = Sn(IV), L = Cl, k = 0; M = Sb(V), L = Cl, k = +1) complexes depends only on the refractive index of the solvents, indicating that interaction of the transition dipole moment with induced dipole moment generated in the surrounding solvent molecules is predominant.

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© 2004 The Chemical Society of Japan
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