Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Regulation of Catalytic Activity of Peptide–Heme Conjugate by Conformational Change with Trifluoroethanol
Seiji SakamotoHidekazu FukushimaKazuaki Kudo
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2006 Volume 35 Issue 6 Pages 584-585

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Abstract

A peptide–heme conjugate in which two α-helix segments were covalently coupled at the heme propionates was designed, and the relationship between the structure and the peroxidase-like catalytic activity was examined. The activity and coordination state of heme were regulated by the conformational change of peptide induced upon the addition of trifluoroethanol.

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© 2006 The Chemical Society of Japan
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