Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Heterometallic Zn2La and ZnLu Complexes Formed by Site-selective Transmetalation of a Dimeric Homotrinuclear Zinc(II) Complex
Shigehisa AkineTakanori TaniguchiTatsuya Nabeshima
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2006 Volume 35 Issue 6 Pages 604-605

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Abstract

Transmetalation of a dimeric homotrinuclear zinc(II) complex [(3-MeOsalamo)2Zn3] with Lu3+ and La3+ afforded heterometallic dinuclear [(3-MeOsalamo)ZnLu]3+ and trinuclear [(3-MeOsalamo)2Zn2La]3+ complexes, respectively, whose structures were determined by X-ray crystallography. The transmetalation process was investigated by 1H NMR titrations.

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© 2006 The Chemical Society of Japan
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