Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Organogel Formation by Self-assembly of Ag(I) and Mono-urea Derivatives Containing Pyridyl Group
Sadao AraiKanako ImazuShiho KusudaIsao YoshihamaMasami TonegawaYukihiro NishimuraKei-ichi KitaharaShigero OishiTetsuo Takemura
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2006 Volume 35 Issue 6 Pages 634-635

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Abstract

The mono-urea derivative 3 derived from 4-(2-aminoethyl)pyridine and dodecyl isocyanate gelled aromatic solvents, such as p-xylene, tetralin, and benzene, in the presence of Ag(I). The complex formation by the coordination of two equivalents of mono-urea 3 to Ag(I) and the intermolecular hydrogen bonding between urea groups plays important roles for the fibrous self-assembly followed by the gelation.

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© 2006 The Chemical Society of Japan
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