Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Efficient Thermal Conversion of Poly(pyridinediylbutadiynylene)s to Nitrogen-containing Microporous Carbon
Masashi KijimaTakayuki OdaTakahisa YamazakiYasunori TazakiJunji Nakamura
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2006 Volume 35 Issue 8 Pages 844-845

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Abstract

Poly(pyridinediylbutadiynylene)s, a conjugated polymer alternatively consisted of the pyridine and butadiyne units, were synthesized by oxidative polycondensation of diethynylpyridine with the Hay catalyst. They converted to microporous carbons in high yields with a high efficiency of fixation of nitrogen by heating up from room temperature to 900 °C under flowing of argon.

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© 2006 The Chemical Society of Japan
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