Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Formation of a Stable Sulfenic Acid by Hydrolysis of a Thionitrate and a Sulfenyl Bromide
Kei GotoKeiichi ShimadaShunsuke FurukawaShinji MiyasakaYusuke TakahashiTakayuki Kawashima
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2006 Volume 35 Issue 8 Pages 862-863

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Abstract

Alkaline hydrolysis of a thionitrate and a sulfenyl bromide bearing a bowl-type steric protection group produced a stable sulfenic acid. This provides a conclusive demonstration of these elementary processes. It was shown that a very efficient steric protection group is necessary to prevent the condensation of the sulfenate anion generated during the hydrolysis.

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© 2006 The Chemical Society of Japan
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