Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Molecular Conductor Based on Reduced π-System Donor: Insulating State of (MeDH-TTP)2AsF6
Hiroyuki NishikawaHiromichi SekiyaAkira FujiwaraTakeshi KodamaIsao IkemotoKoichi KikuchiJun-ichi YamadaHiroki OshioKensuke KobayashiSyuma YasuzukaKeizo Murata
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2006 Volume 35 Issue 8 Pages 912-913

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Abstract

The transport properties of (MeDH-TTP)2AsF6, which crystallized in the κ-type structure, were investigated and found to be semiconductive with a small activation energy. ESR measurements suggested that the insulating state below 40 K should be antiferromagnetic, similarly to the Mott transition system represented by quasi-two-dimensional κ-ET [ET = bis(ethylenedithio)tetrathiafulvalene] salts.

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© 2006 The Chemical Society of Japan
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