Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Fluoride Complexation of Element 104, Rutherfordium (Rf), Investigated by Cation-exchange Chromatography
Yasuo IshiiAtsushi ToyoshimaKazuaki TsukadaMasato AsaiHayato ToumeIchiro NishinakaYuichiro NagameSunao MiyashitaTomotaka MoriHideo SuganumaHiromitsu HabaMasami SakamakiShin-ichi GotoHisaaki KudoKazuhiko AkiyamaYasuji OuraHiromichi NakaharaYuki TashiroAtsushi ShinoharaMatthias SchädelWilly BrüchleValeria PershinaJens V. Kratz
Author information
JOURNAL RESTRICTED ACCESS

2008 Volume 37 Issue 3 Pages 288-289

Details
Abstract

We report on new and much more precise cation-exchange data of element 104, rutherfordium (Rf), in the fluoride ion concentration [F] range of 5.29×10−5−1.04×10−3 M. The result based on one-atom-at-a-time chemistry clearly demonstrates that the distribution coefficients (Kd) decrease with increasing [F], suggesting successive fluoride complexation of Rf. The complexation of Rf is briefly discussed in terms of fully relativistic density functional calculation theory.

Content from these authors

This article cannot obtain the latest cited-by information.

© 2008 The Chemical Society of Japan
Previous article Next article
feedback
Top