Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Reversible Single Crystal-to-Amorphous Phase Transition upon Dehydration–Rehydration and Associated Magnetism in [MnII(enH)(H2O)][CrIII(CN)6]·H2O
Yusuke YoshidaKatsuya InoueMohamedally Kurmoo
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2008 Volume 37 Issue 5 Pages 504-505

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Abstract

We report the rare occurrence of a reversible loss of crystallinity upon dehydration and regain upon rehydration by in situ X-ray diffraction on a single crystal of [MnII(enH)(H2O)][CrIII(CN)6]·H2O and the associated thermal and magnetic properties characterized by an increase of the Curie temperature of the soft ferrimagnet from 42 to 75 K.

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© 2008 The Chemical Society of Japan
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