Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
1,3-Digermabicyclo[1.1.0]butane with an Inverted Bridge Ge–Ge σ Bond
Takeaki IwamotoDongzhu YinSven BoomgaardenChizuko KabutoMitsuo Kira
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2008 Volume 37 Issue 5 Pages 520-521

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Abstract

1,3-Digermabicyclo[1.1.0]butane 2 was synthesized as yellow crystals. The molecular structure, 13C NMR and UV–vis spectra, and theoretical calculations have revealed that 2 is a typical long bond isomer, similarly to the silicon congener 1. Structural comparison between 1 and 2 is achieved.

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© 2008 The Chemical Society of Japan
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