Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Self-aggregation of Synthetic Zinc Chlorophyll Derivatives Possessing Fluoroalkyl Chains in Liquid Carbon Dioxide as Models of Green Photosynthetic Bacterial Antennae
Reiko ShibataKazuhide KoikeHisao HoriHitoshi Tamiaki
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2008 Volume 37 Issue 5 Pages 532-533

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Abstract

Zinc chlorophyll derivatives possessing (multi)-perfluoroalkyl chain(s) in the 17-propionate residue were dissolved in liquid carbon dioxide to form their oligomers (=J-aggregates), while the alkyl-type analog was insoluble in the medium. These results indicated solubilization and stabilization of their supramolecules by an interaction between the perfluoroalkyl substituents and liquid carbon dioxide.

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© 2008 The Chemical Society of Japan
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