Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Electrophilic Substitution of Platinum(II) Complexes with Thiophene Derivatives
Atsunori MoriAtsushi SugieHirotoshi FurukawaYuji SuzakiKohtaro OsakadaMunetaka Akita
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2008 Volume 37 Issue 5 Pages 542-543

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Abstract

The reaction of aryl(halo)platinum(II)(bpy) complexes with thiophene derivatives causes novel electrophilic substitution in the presence of AgNO3/KF as an activator to form thienyl complexes in 65–91% yields. The related reaction with (dihalo)platinum(II) also takes place to afford dithienylplatinum(II) complexes.

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© 2008 The Chemical Society of Japan
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