Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Redox Behavior of Ruthenium(Bipyridine)(Terpyridine)(Carbonyl) Complex-modified Carbon Electrode and Reactivity toward Electrochemical Reduction of CO2
Yuhei TsukaharaTohru WadaKoji Tanaka
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2010 Volume 39 Issue 11 Pages 1134-1135

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Abstract

Electrochemical reduction of a diazonium complex [Ru(bpy)(trpy-ph-N2+)(CO)](PF6)3 ([1](PF6)3) (bpy = 2,2′-bipyridine, trpy-ph-N2+ = 4-(2,2′:6′,2′′-terpyridine-4′-yl)benzenediazonium) using a GC electrode forms multilayer films of the complexes on the electrode surface, on which the reduced form of the complex showed strong affinity toward CO2.

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© 2010 The Chemical Society of Japan
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