Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Z-Selective Horner–Wadsworth–Emmons-type Reaction Using a 10-P-5 Phosphorane Bearing Bidentates Derived from 1-Naphthol
Satoshi KojimaJun-ya ArimuraKazumasa Kajiyama
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2010 Volume 39 Issue 11 Pages 1138-1139

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Abstract

A Horner–Wadsworth–Emmons-type 10-P-5 phosphorane reagent bearing bidentate ligands from 1-naphthol was prepared and examined in the olefination of aldehydes. Z-Selectivity was generally high except for the case of 3-phenylpropanal, and acetophenone was also found to react with relatively high selectivity.

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© 2010 The Chemical Society of Japan
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