Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Nitrogen-15 NMR Spectroscopy of Sugar Sensor with B–N Interaction as a Key Regulator of Colorimetric Signals
Yuya EgawaYoshiyuki TanakaRyota GotohSatoshi NiinaYu KojimaNaoki ShimomuraHiroko NakagawaToshinobu SekiJun-ichi Anzai
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2010 Volume 39 Issue 11 Pages 1188-1189

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Abstract

Nitrogen-15 NMR spectroscopy showed strongly upfield values of the chemical shift for one of the azo nitrogen atoms of a boronic-acid-appended azo dye: this indicated the formation of a boron–nitrogen (B–N) dative bond. The B–N dative bond was cleaved by sugar addition.

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© 2010 The Chemical Society of Japan
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