Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
An Acid-stable Organoruthenium Complex Suitable as a Bidentate Building Block
Chunbai ZhengDaisuke InokiTakahiro MatsumotoSeiji Ogo
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2010 Volume 39 Issue 2 Pages 130-131

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Abstract

A new, water-soluble organoruthenium(II) sulfato complex [RuII(SO4)(Bz^py)] {1, Bz^py = 2-(pentamethylbenzyl)pyridine} has been synthesized and is stable at pH from 2.0 to 8.0. This complex has a bidentate sulfato ligand as a leaving group and is a good building block for “concerto catalysis”: a new way of thinking in catalysis that bridges hetero- and homogeneous catalysis.

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© 2010 The Chemical Society of Japan
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