Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
MnIII Salen-type Single-molecule Magnet Fixed in a Two-dimensional Network
Chihiro Kachi-TerajimaErina MoriTasuku EibaToshiaki SaitoChikahide KanadaniTakafumi KitazawaHitoshi Miyasaka
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2010 Volume 39 Issue 2 Pages 94-95

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Abstract

A two-dimensional network compound, [{Mn(saltmen)}4{Co(CN)6}](ClO4)·9H2O (2) (saltmen2− = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate)), was synthesized. Magnetic measurements characterized the [Mn2(saltmen)2]2+ subunit as a single-molecule magnet with an ST = 4 spin ground state, indicating that the MnIII dimer is magnetically isolated not only by the diamagnetic [Co(CN)6]3− unit but also by the space between the layers.

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© 2010 The Chemical Society of Japan
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