Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Preparation of Ester-group Substituted Allylic Zinc by Palladium-catalyzed Umpolung of γ-Acyloxy-α,β-unsaturated Ester by Bis(iodozincio)methane
Shizue UenoMutsumi SadaSeijiro Matsubara
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2010 Volume 39 Issue 2 Pages 96-97

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Abstract

Treatment of γ-acyloxy-α,β-unsaturated ester with bis(iodozincio)methane in the presence of palladium catalyst gave an allylic zinc carrying an ester group; the allylic zinc, which is prepared by this umpolung process, reacts with ketones regioselectively.

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© 2010 The Chemical Society of Japan
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