Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
An Unexpected Guanidine-catalyzed Amination Reaction Leading to (Z)-α-Aminocinnamamides
Bo JiangShu-Jiang Tu
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2010 Volume 39 Issue 3 Pages 210-211

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Abstract

An unexpected guanidine-catalyzed amination reaction between 4-(arylmethylidene)-2-phenyloxazol-5-ones and N,N-dimethylformamide in water for selective synthesis of new (Z)-α-aminocinnamamides was described. This method has the advantages of short synthetic route, operational simplicity, and minimal environment impact.

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© 2010 The Chemical Society of Japan
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