2011 Volume 40 Issue 10 Pages 1184-1186
A novel mixed-valence Cu(I)–Cu(II) coordination polymer with an infinite one-dimensional (1-D) structure, [CuI4CuIII4(Mor-dtc)2(CH3CN)2]n (Mor-dtc−: morpholine dithiocarbamate), was prepared and structurally characterized by X-ray diffraction. This complex consists of a mononuclear copper(II) unit of [CuII(Mor-dtc)2] and a tetranuclear Cu(I) unit of [Cu4I4(CH3CN)2]. It also shows semiconductive behaviors with a relatively small activation energy, which was revealed by impedance analysis.
This article cannot obtain the latest cited-by information.