Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Synthesis and Conducting Properties of a New Mixed-valence Cu(I)–Cu(II) 1-D Coordination Polymer Bridged by Morpholine Dithiocarbamate
Kyung Ho KimTakashi UetaTakashi OkuboShinya HayamiHaruho AnmaKazuya KatoTetsuya ShimizuJyunji FujimoriMasahiko MaekawaTakayoshi Kuroda-Sowa
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2011 Volume 40 Issue 10 Pages 1184-1186

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Abstract

A novel mixed-valence Cu(I)–Cu(II) coordination polymer with an infinite one-dimensional (1-D) structure, [CuI4CuIII4(Mor-dtc)2(CH3CN)2]n (Mor-dtc: morpholine dithiocarbamate), was prepared and structurally characterized by X-ray diffraction. This complex consists of a mononuclear copper(II) unit of [CuII(Mor-dtc)2] and a tetranuclear Cu(I) unit of [Cu4I4(CH3CN)2]. It also shows semiconductive behaviors with a relatively small activation energy, which was revealed by impedance analysis.

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© 2011 The Chemical Society of Japan
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