Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
Formation of a Unique Fluorosilene–KF Complex Bearing Bulky Substituents
Eiko MiedaTakahiro SasamoriShohei SaseKei GotoNorihiro Tokitoh
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2011 年 40 巻 2 号 p. 196-197

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We report here the attempted synthesis of a stable 1-fluoro-2-hydrosilene bearing a Bpq group, which is a bulky aryl group bearing a cavity-shaped framework. We have successfully synthesized an overcrowded benzyldifluorosilane as a precursor. Treatment of the benzyldifluorosilane with 2 equiv of t-BuOK in THF afforded the corresponding benzyl anion, the structure of which showed a unique feature as a fluorosilene–KF complex.

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© 2011 The Chemical Society of Japan
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