Paper in Celebration for the 2010 Nobel Prize in Chemistry
Pd-catalyzed Highly Regio- and Stereocontrolled Direct Alkenylation of Electron-deficient Polyfluoroarenes
2011 Volume 40 Issue 9 Pages 978-979
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2011 Volume 40 Issue 9 Pages 978-979
An effective and reliable method for Pd-catalyzed highly regio- and stereocontrolled direct alkenylation of electron-deficient polyfluoroarenes with alkenyl iodides has been developed. The advantages of this reaction are its high regio- and stereoselectivity, mild reaction temperature (70 °C), and the use of readily available Pd(PPh3)4. This approach provides a useful access to polyfluoroarylated derivatives of interest in both life and materials science.
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