Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Synthesis and Adsorption Properties of Azulene-containing Porous Interdigitated Framework
Keisuke KishidaSatoshi HorikeKeiji NakagawaSusumu Kitagawa
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2012 Volume 41 Issue 4 Pages 425-426

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Abstract

A porous interdigitated 2D coordination framework {[Zn(azdc)(bpy)]·DMF}n (azdc: 1,6-azulenedicarboxylate; bpy: 4,4′-bipyridyl; DMF: N,N-dimethylformamide) was synthesized and structurally characterized. By comparing with its constitutional isomer, [Zn(azdc)(bpy)]n showed stronger H2O interaction which was induced by polarized azulene moiety.

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© 2012 The Chemical Society of Japan
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