Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
The First Example for Cyanation of Arylboronic Acids with Nontoxic and Inexpensive K4[Fe(CN)6]
Xinzhe TianYanpei SunChuanhua DongKaixuan ZhangTengfei LiangYu ZhangChaodong Hou
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Volume 41 (2012) Issue 7 Pages 719-721

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Abstract

Nontoxic and inexpensive K4[Fe(CN)6] is first introduced as a cyanating agent to cyanation of arylboronic acids. The present method is simple, practical, and allowed a wide range of substrates including functionalized phenylboronic acids, 1-naphthylboronic acid as well as heterocyclic boronic acids to be smoothly converted into the corresponding products in moderate to high yields.

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© 2012 The Chemical Society of Japan
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