Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Synthesis of a Base-stabilized (Chlorogermyl)metallogermylene and Its Photochemical Conversion to a (Chlorogermyl)germylyne Complex
Shin-ya TashitaTakahito WatanabeHiromi Tobita
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Supplementary material

2013 Volume 42 Issue 1 Pages 43-44

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Abstract

An NHC-stabilized (chlorogermyl)metallogermylene [Cp(CO)3WGe{GeCl(Mes)2}(MeIiPr)] (NHC: N-heterocyclic carbene, MeIiPr: 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, Mes: mesityl) was synthesized by the reaction of [Na(dme)2][CpW(CO)3] (dme: 1,2-dimethoxyethane) with (chlorogermyl)chlorogermylene [GeCl{GeCl(Mes)2}(MeIiPr)]. Irradiation to a solution of the metallogermylene with an Hg lamp afforded an NHC-stabilized (chlorogermyl)germylyne complex [Cp(CO)2W≡Ge{GeCl(Mes)2}(MeIiPr)].

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© 2013 The Chemical Society of Japan
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