Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Formal anti-Markovnikov Hydroamination of Terminal Aryl Alkynes with Pinacolborane and Hydroxylamines via Zr/Cu Sequential Catalysis
Ryosuke SakaeKoji HiranoTetsuya SatohMasahiro Miura
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JOURNALS OPEN ACCESS

2013 Volume 42 Issue 10 Pages 1128-1130

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Abstract

We have developed sequential Zr/Cu catalysis involving regioselective hydroboration and electrophilic amination for the formal anti-Markovnikov hydroamination of terminal aryl alkynes. The reaction system can provide a facile access to enamines from terminal acetylenes with high regioselectivity under mild conditions.

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© 2013 The Chemical Society of Japan
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