Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
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Photocrosslinking of Fullerene Vesicles that Prevents Phase Transition and Decreases Water Permeation
Koji HaranoAkimitsu NaritaEiichi Nakamura
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JOURNALS OPEN ACCESS

2013 Volume 42 Issue 10 Pages 1176-1178

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Abstract

A bilayer vesicle made of pentasubstituted [60]fullerene anions was photocrosslinked under aerobic conditions. The crosslinked bilayer became watertight because the crosslinking suppressed the phase transition of the bilayer, reduced the mobility of the fullerene molecules, and hence, reduced the speed of water permeation through the bilayer.

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© 2013 The Chemical Society of Japan
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