Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Cobalt-catalyzed Branched-selective Addition of Aromatic Ketimines to Styrenes under Room-temperature Conditions
Jinghua DongPin-Sheng LeeNaohiko Yoshikai
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JOURNALS OPEN ACCESS

2013 Volume 42 Issue 10 Pages 1140-1142

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Abstract

An improved cobalt-based catalytic system has been developed for the branched-selective addition of aromatic ketimines to styrenes. With an appropriate combination of triarylphosphine and the Grignard reagent, the reaction takes place smoothly at room temperature to afford 1,1-diarylethane derivatives with high regioselectivity.

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© 2013 The Chemical Society of Japan
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