Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Identification of Alkenyl- and Arylpalladium Hydrides with the Aid of Hydrosilanes
Tieqiao ChenYongbo ZhouShuang-Feng YinYalei ZhaoMidori GotoLi-Biao Han
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2013 Volume 42 Issue 10 Pages 1227-1229

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Abstract

For the first time, the long-proposed thermodynamically unstable catalytic intermediates alkenyl and aryl complexes sp2C–Pd–H have been isolated through the reduction of the palladium acetates with hydrosilanes and subsequent stabilization of the hydridopalladiums with hydrosilanes. The structures of these hydridopalladiums were established by X-ray analysis.

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© 2013 The Chemical Society of Japan
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