Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Iron Corrole-catalyzed [4 + 2] Cycloaddition of Dienes and Aldehydes
Toru KuwanoTakuya KurahashiSeijiro Matsubara
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2013 Volume 42 Issue 10 Pages 1241-1243

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Abstract

We have developed cationic iron(IV) corrole-catalyzed formal hetero-Diels–Alder reaction of aldehydes with dienes, which opens the way for divergent synthesis of pyrans. The potential utility of the catalyst was also demonstrated by carrying out cycloaddition of α,β-unsaturated aldehyde with a diene to give pyran selectively. Furthermore, the catalytic reactivity of iron corrole complex on the cycloaddition was determined by comparing that of iron porphyrin complex.

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© 2013 The Chemical Society of Japan
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