Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
Nonplanar and Dynamic Structures of 1,8-Anthrylene–Ethenylene Cyclic Dimers
Masataka InoueTetsuo IwanagaShinji Toyota
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Volume 42 (2013) Issue 12 Pages 1499-1501

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Abstract

The title cyclic compounds, synthesized by cross-coupling reactions, have nonplanar frameworks, as revealed by X-ray analysis and DFT calculations. The barrier to exchange between the nonplanar structures of the mesityl derivative was determined to be 34 kJ mol−1 by a dynamic NMR method.

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© 2013 The Chemical Society of Japan
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