Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Syntheses of Aldol Products and Cyanohydrins from Carboxylic Acids Using Hydrosilanes, Organosilicon Reagents, and Indium Triiodide Catalyst
Yoshihiro InamotoYoshihiro NishimotoMakoto YasudaAkio Baba
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2013 Volume 42 Issue 12 Pages 1551-1553

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Abstract

Carboxylic acids were applied to an indium triiodide-catalyzed reductive aldol reaction and a reductive cyanation in order to produce aldol adducts and cyanohydrins, respectively, in which the separate addition of two kinds of hydrosilanes was crucial in combination with either ketene silyl acetals or silyl cyanides.

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© 2013 The Chemical Society of Japan
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