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Chemistry Letters
Vol. 42 (2013) No. 12 P 1548-1550

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http://doi.org/10.1246/cl.130822

Letter

A New Bis-fused π-Electron Donor Composed of Tetrathiafulvalene and 2-(Xanthen-9-ylidene)-1,3-dithiole

Minami Kato1), Takashi Shirahata1), Yohji Misaki1) 2)

1) Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University 2) Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University

Released on J-STAGE 20131205   [Advance Publication] Released 20130928
Received 20130905  

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Derivatives of a new bis-fused TTF analogue 2 composed of TTF and 2-(xanthen-9-ylidene)-1,3-dithiole have been synthesized. Cyclic voltammograms of 2 are composed of three pairs of redox waves, of which the third redox wave corresponds to a two-electron-transfer process. X-ray structure analysis of the ReO4− salt of bis(methylthio)-2 [(2b)ReO4(DCE)0.5] revealed that the 2b molecules form a dimerized one-dimensional stack.

Copyright © 2013 The Chemical Society of Japan
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