Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
Acetals of N,N-Dimethylformamides: Ambiphilic Behavior in Converting Carbon Dioxide to Dialkyl Carbonates
Yuki TakadaAki MatsuokaYa DuHiroshi NakaSusumu Saito
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2013 Volume 42 Issue 2 Pages 146-147

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Abstract

Carbon dioxide is immobilized into dialkyl carbonate using acetals of N,N-dimethylformamide under atmospheric pressure. No special treatment with tailor-made catalysts is needed. Use of dimethyl sulfoxide as a solvent is critical. An ambiphilic mechanism is proposed for the direct synthesis of dialkyl carbonates from acetals and carbon dioxide.

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© 2013 The Chemical Society of Japan
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