Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
One-pot, Radiation-induced Graft Polymerization of Vinylsulfonic Acid onto Poly(ether ether ketone) and High Proton Conductivity of Its Membrane
Katsuyuki TakahashiHiroyuki Nishide
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Volume 42 (2013) Issue 3 Pages 218-219

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Abstract

A poly(vinylsulfonic acid) (PVSA)-grafted poly(ether ether ketone) (PEEK) was simply prepared by one-pot, γ-ray radiation-induced graft polymerization of the vinylsulfonic acid (VSA) solution dissolving PEEK. The VSA-highly-grafted PEEK membrane possessed high ion exchange capacity (e.g., 7.2 mequiv g−1) and showed proton conductivity in the order of 10−1 and 10−3–10−6 S cm−1 under hydrated and nonhumidified conditions, respectively.

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© 2013 The Chemical Society of Japan
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