Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
Facile Method of Halogen Exchange between Au(Cl)(L) and MeC(O)X (L = PPh3 and IPr; X = Br and I) via σ-Bond Metathesis Supported by DFT Calculation
Atsushi SanagawaHitoshi KuniyasuTakanori IwasakiNobuaki KambeKaran BobuatongMasahiro Ehara
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Volume 42 (2013) Issue 8 Pages 831-832

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Abstract

Complexes with the formula Au(X)(L) (X = Br and I; L = PPh3 and IPr) were conveniently prepared by a quite simple procedure using the treatment of Au(Cl)(L) with MeC(O)X and the subsequent evaporation under reduced pressure. The mechanistic study by DFT calculation with M06 functional supported that the reaction proceeded through σ-bond metathesis, where Cl atom underwent a more roundabout course than Br atom did.

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© 2013 The Chemical Society of Japan
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