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Chemistry Letters
Vol. 43 (2014) No. 12 P 1829-1831

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http://doi.org/10.1246/cl.140731

Letter

Addition of appropriate amounts of Me2S unusually accelerated the hydrosilylation of aldehydes catalyzed by [Ru3(CO)7(Acy)] (1, Acy: µ3235-acenaphthylene). The reduction of ketones was completely suppressed under the reaction conditions. The highly selective reduction of aldehydes in the presence of ketones was achieved via a nonconventional mechanism.

Copyright © 2014 The Chemical Society of Japan

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