Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
Photosubstitution of Dicyanoarenes by Hypervalent Allylsilicon Reagents via Photoinduced Electron Transfer
Daisuke MatsuokaYutaka Nishigaichi
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Volume 43 (2014) Issue 4 Pages 559-561

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Abstract

Photosubstitution of dicyanoarenes with hypervalent allylsilicon reagents in the presence of anthracene efficiently proceeded to afford the allyl-substituted product in moderate to good yields. The efficiency for the present photoreaction was much higher than that for the tetracoordinate allylsilanes, because hypervalent allylsilicon reagents possess lower oxidation potential than the tetracoordinate ones, which resulted in more efficient photoinduced electron-transfer process.

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© 2014 The Chemical Society of Japan
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