Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
Letter
Asymmetric Aldol Reaction of Formaldehyde Catalyzed by Diarylprolinol
Yusuke YasuiMeryem BenohoudItaru SatoYujiro Hayashi
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2014 Volume 43 Issue 4 Pages 556-558

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Abstract

The asymmetric cross-aldol reaction of formaldehyde with aldehyde pronucleophiles, catalyzed by trifluoromethyl-substituted diarylprolinol 1, was accomplished to directly afford α-hydroxymethyl-substituted aldehydes in good yield with excellent enantioselectivity.

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© 2014 The Chemical Society of Japan
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