Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Silica-supported Tripod Triarylphosphines: Application to Palladium-catalyzed Borylation of Chloroarenes
Tomohiro IwaiTomoya HaradaRyotaro TanakaMasaya Sawamura
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2014 Volume 43 Issue 5 Pages 584-586

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Abstract

Silica-supported tripod triarylphosphines that have a Ph3P-type core tripodally immobilized on a silica surface enabled the Pd-catalyzed borylation of chloroarenes with bis(pinacolato)diboron under mild conditions. The immobilization in tripod was crucial for the excellent performance of the Ph3P-based ligands.

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© 2014 The Chemical Society of Japan
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