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Chemistry Letters
Vol. 43 (2014) No. 5 P 708-710




A new cyclic tetrathiafulvalene (TTF) tetramer 1 was synthesized. The cyclic voltammogram of 1 consists of four pairs of two-electron redox waves. UV–vis–NIR spectra of the oxidative species of 1 suggest that 12+, 14+, and 16+ possibly adopt two pairs of dimeric TTF structures that interact with each other through the so-called side-by-side interaction.

Copyright © 2014 The Chemical Society of Japan

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