Chemistry Letters
Letter
Cyclic TTF Tetramer Linked by Methylenedithio Spacers
Ken-ichi NakamuraYuuki OkadaTakashi ShirahataYohji Misaki
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Volume 43 (2014) Issue 5 Pages 708-710

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Abstract

A new cyclic tetrathiafulvalene (TTF) tetramer 1 was synthesized. The cyclic voltammogram of 1 consists of four pairs of two-electron redox waves. UV–vis–NIR spectra of the oxidative species of 1 suggest that 12+, 14+, and 16+ possibly adopt two pairs of dimeric TTF structures that interact with each other through the so-called side-by-side interaction.

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© 2014 The Chemical Society of Japan
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