Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Electrochiroptical Response in Aqueous Media: 9,10-Dihydrophenanthrene-9,10-diyl Dications with Michlar’s Hydrol Blue Chromophores Attached with Oligoethylene Glycol Units
Takanori SuzukiKeisuke HanadaRyo KatoonoYusuke IshigakiSho HigasaHiroki HiguchiHirotsugu KikuchiKenshu FujiwaraHidetoshi YamadaTakanori Fukushima
Author information
JOURNAL RESTRICTED ACCESS
Supplementary material

2014 Volume 43 Issue 7 Pages 982-984

Details
Abstract

Upon electrochemical oxidation of configurationally stable biphenyl-based electron donors (Rax)-1a and -1b to butane-1,4-diyl dications (M)-2a2+ and -2b2+, drastic changes were induced not only in UV–vis but also in CD spectra. Because of the hydrophilic oligoethylene glycol units on the amino nitrogens, (Rax)-1b and (M)-2b2+ are soluble in water, thus realizing the electrochiroptical behavior not only in organic solvents but also in aqueous media.

Information related to the author

This article cannot obtain the latest cited-by information.

© 2014 The Chemical Society of Japan
Previous article Next article
feedback
Top