Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Synthesis of Polyamide Carboxylic Acid Containing Amino Acid via Amidocarbonylation
Yusuke AminoKunisuke Izawa
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2017 Volume 46 Issue 11 Pages 1635-1638

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Abstract

Herein, we synthesize and characterize polyamide carboxylic acids containing amino acid by polymerization via the amidocarbonylation of bifunctional components. Cobalt-catalyzed hydroformylation followed by intermolecular amidocarbonylation of alkenoic acid amide yields the head-to-tail polyamide carboxylic acid with a structure resembling that of γ-polyglutamic acid constructed from the long-chain homologous of glutamic acid. Conversely, palladium-catalyzed amidocarbonylation of an equimolar amount of diamide and dialdehyde yields head-to-head polyamide carboxylic acid that contains the linear long-chain homolog of bis-α-amino acid.

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© 2017 The Chemical Society of Japan
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