Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
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Visualization of Chiral Binaphthyl Recognition by Atroposelective Antibodies with Thermoresponsive Polymers
Tomoki OdakaTakuma AdachiAkira HaradaHiroyasu Yamaguchi
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2017 Volume 46 Issue 8 Pages 1173-1175

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Abstract

Chiral recognition of monoclonal antibodies (mAbs) to binaphthyl derivatives (BNs) is visualized utilizing poly-N-isopropylacrylamide (pNIPAM) bearing a BN moiety. The affinity of an anti-BN (S) antibody to BN (S) is retained even when BN (S) is attached to the center of the pNIPAM main chain. The addition of the anti-BN (S) antibody in an atroposelective manner suppresses the aggregation of pNIPAM-BN (S).

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© 2017 The Chemical Society of Japan
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