Chemistry Letters
Online ISSN : 1348-0715
Print ISSN : 0366-7022
ISSN-L : 0366-7022
Letter
Ordered Mesoporous CuZn/HPS Catalysts for the Chemoselective Hydrogenation of Dimethyl Adipate to 1,6-Hexanediol
Yujun ZhaoZiyuan GuoHaojie ZhangYuxi XuYue WangJian ZhangYan XuShengping WangXinbin Ma
Author information
JOURNALS RESTRICTED ACCESS

2017 Volume 46 Issue 8 Pages 1079-1082

Details
Abstract

A highly efficient ordered mesoporous CuZn/hierarchical porous silica (HPS) catalyst was prepared by an impregnation–ammonia evaporation method. The presence of Zn species prompted the dispersion of copper species and the formation of more Cu+ species in reduced catalyst. Moreover, the larger mesopores in HPS significantly enhanced the accessibility of active sites for the dimethyl adipate adsorption. The cooperative effect of zinc species and the HPS structure contributed to the superior catalytic performances of CuZn/HPS in dimethyl adipate hydrogenation.

Information related to the author

This article cannot obtain the latest cited-by information.

© 2017 The Chemical Society of Japan
Previous article Next article
feedback
Top